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The Science of Nature -     

Environmental and health effects of nanomaterials in nanotextiles and façade coatings

Engineered nanomaterials (ENM) are expected to hold considerable potential for products that offer improved or novel functionalities. For example, nanotechnologies could open the way for the use of textile products outside their traditional fields of applications, for example, in the construction, medical, automobile, environmental and safety technology sectors. Consequently, nanotextiles could become ubiquitous in industrial and consumer products in future. Another ubiquitous field of application for ENM is fa?ade coatings. The environment and human health could be affected by unintended release of ENM from these products. The product life cycle and the product design determine the various environmental and health exposure situations. For example, ENM unintentionally released from geotextiles will probably end up in soils, whereas ENM unintentionally released from T-shirts may come into direct contact with humans and end up in wastewater. In this paper we have assessed the state of the art of ENM effects on the environment and human health on the basis of selected environmental and nanotoxicological studies and on our own environmental exposure modeling studies. Here, we focused on ENM that are already applied or may be applied in future to textile products and fa?ade coatings. These ENM's are mainly nanosilver (nano-Ag), nano titanium dioxide (nano-TiO(2)), nano silica (nano-SiO(2)), nano zinc oxide (nano-ZnO), nano alumina (nano-Al(2)O(3)), layered silica (e.g. montmorillonite, Al(2)[(OH)(2)/Si(4)O(10)]nH(2)O), carbon black, and carbon nanotubes (CNT). Knowing full well that innovators have to take decisions today, we have presented some criteria that should be useful in systematically analyzing and interpreting the state of the art on the effects of ENM. For the environment we established the following criteria: (1) the indication for hazardous effects, (2) dissolution in water increases/decreases toxic effects, (3) tendency for agglomeration or sedimentation, (4) fate during waste water treatment, and (5) stability during incineration. For human health the following criteria were defined: (1) acute toxicity, (2) chronic toxicity, (3) impairment of DNA, (4) crossing and damaging of tissue barriers, (5) brain damage and translocation and effects of ENM in the (6) skin, (7) gastrointestinal or (8) respiratory tract. Interestingly, some ENM might affect the environment less severely than they might affect human health, whereas the case for others is vice versa. This is especially true for CNT. The assessment of the environmental risks is highly dependent on the respective product life cycles and on the amounts of ENM produced globally.     

Quantifying disturbance effects on vegetation carbon pools in mountain forests based on historical data

Although the terrestrial carbon budget is of key importance for atmospheric CO₂ concentrations, little is known on the effects of management and natural disturbances on historical carbon stocks at the regional scale. We reconstruct the dynamics of vegetation carbon stocks and flows in forests across the past 100 years for a valley in the eastern Swiss Prealps using quantitative and qualitative information from forest management plans. The excellent quality of the historical information makes it possible to link dynamics in growing stocks with high-resolution time series for natural and anthropogenic disturbances. The results of the historical reconstruction are compared with modelled potential natural vegetation. Forest carbon stock at the beginning of the twentieth century was substantially reduced compared to natural conditions as a result of large scale clearcutting lasting until the late nineteenth century. Recovery of the forests from this unsustainable exploitation and systematic forest management were the main drivers of a strong carbon accumulation during almost the entire twentieth century. In the 1990s two major storm events and subsequent bark beetle infestations significantly reduced stocks back to the levels of the mid-twentieth century. The future potential for further carbon accumulation was found to be strongly limited, as the potential for further forest expansion in this valley is low and forest properties seem to approach equilibrium with the natural disturbance regime. We conclude that consistent long-term observations of carbon stocks and their changes provide rich information on the historical range of variability of forest ecosystems. Such historical information improves our ability to assess future changes in carbon stocks. Further, the information is vital for better parameterization and initialization of dynamic regional scale vegetation models and it provides important background for appropriate management decisions.     

Polychlorinated biphenyls (PCBs) in indoor air originating from sealants in contaminated and uncontaminated apartments within the same housing estate

Twenty-four congeners of polychlorinated biphenyls (PCBs) were measured in 83 air samples and 20 elastic sealants samples of apartments with PCB-containing sealants. In addition, PCBs were measured in 21 air samples from reference apartments located in an uncontaminated section of the same estate. The PCB_tot levels in the air of the contaminated section were 168-3843 ng m⁻³ (mean: 1030 ng m⁻³), while the mean levels in the reference apartments were 6.03 ng m⁻³. The sum of the 24 measured PCB congeners in sealants from the contaminated section was 187-221 680 mg kg⁻¹. Principal component analysis revealed four groups among the sealant samples with different congener compositions, only two of which were clearly similar to known PCB mixtures, while two were not. Significant correlations and intercorrelations were observed between the lower chlorinated congeners in air and sealant, e.g. for PCB 28_air and 28_seal (p = 0.04) and for PCB 28_air and 52_air, 52_seal. However, no correlation was observed between the lower chlorinated congeners and the sums of PCB (∑PCB₆ or ∑PCB₂₄) or the higher chlorinated congeners. Analysis of air concentrations in relation to questionnaire data indicated that the indoor air levels could be reduced by increased cleaning and airing frequencies.     

A dynamic modelling approach for estimating critical loads of nitrogen based on plant community changes under a changing climate

A dynamic model of forest ecosystems was used to investigate the effects of climate change, atmospheric deposition and harvest intensity on 48 forest sites in Sweden (n = 16) and Switzerland (n = 32). The model was used to investigate the feasibility of deriving critical loads for nitrogen (N) deposition based on changes in plant community composition. The simulations show that climate and atmospheric deposition have comparably important effects on N mobilization in the soil, as climate triggers the release of organically bound nitrogen stored in the soil during the elevated deposition period. Climate has the most important effect on plant community composition, underlining the fact that this cannot be ignored in future simulations of vegetation dynamics. Harvest intensity has comparatively little effect on the plant community in the long term, while it may be detrimental in the short term following cutting. This study shows: that critical loads of N deposition can be estimated using the plant community as an indicator; that future climatic changes must be taken into account; and that the definition of the reference deposition is critical for the outcome of this estimate.     

Integrated pollution prevention and control in large industrial installations on the basis of best available techniques – The Sevilla Process

With respect to emissions from industry, the IPPC Directive is one of the key instruments of the environmental legislation of the European Union. The purpose of this Directive is to achieve integrated pollution prevention and control from large industrial installations. The conditions of required permits have to be based on Best Available Techniques (BAT). In 1997, the so-called Sevilla Process was established to develop these BAT. Since then, 33 Best Available Techniques REFerence Documents (BREFs) were drafted, adopted and published. This Sevilla Process with its actors is described. The BREFs are unique documents containing ambitious consumption and emission levels which cannot be found anywhere else.